Solubility Quotes (2 quotes)
Compounds formed by chemical attraction, possess new properties different from those of their component parts... chemists have long believed that the contrary took place in their combination. They thought, in fact, that the compounds possessed properties intermediate between those of their component parts; so that two bodies, very coloured, very sapid, or insapid, soluble or insoluble, fusible or infusible, fixed or volatile, assumed in chemical combination, a shade or colour, or taste, solubility or volatility, intermediate between, and in some sort composed of, the same properties which were considered in their principles. This is an illusion or error which modern chemistry is highly interested to overthrow.
Quoted in A General System of Chemical Knowledge (1804), Vol. I, trans. W. Nicholson, 102-3.
Every arsenate has its corresponding phosphate, composed according to the same proportions, combined with the same amount of water of crystallization, and endowed with the same physical properties: in fact, the two series of salts differ in no respect, except that the radical of the acid in one series in phosphorus, while in the other it is arsenic.
The experimental clue he used forming his law of isomerism. Originally published in 'Om Förhållandet emellan chemiska sammansättningen och krystallformen hos Arseniksyrade och Phosphorsyrade Salter', (On the Relation between the Chemical Composition and Crystal Form of Salts of Arsenic and Phosphoric Acids), Kungliga Svenska vetenskapsakademiens handlingar (1821), 4. Translation as shown in Joseph William Mellor, A Comprehensive Treatise on Inorganic and Theoretical Chemistry (1922), Vol. 1, 652. A very similar translation (“the same physical properties” is replaced with “nearly equal solubilities in water and acids”) is in F. Szabadváry article on 'Eilhard Mitscherlich' in Charles Coulston Gillispie (ed.), Dictionary of Scientific Biography (1974), Vol. 9, 424; perhaps from J.R. Partington, A History of Chemistry, Vol. 4 (1964), 210.
In science it often happens that scientists say, 'You know that's a really good argument; my position is mistaken,' and then they would actually change their minds and you never hear that old view from them again. They really do it. It doesn't happen as often as it should, because scientists are human and change is sometimes painful. But it happens every day. I cannot recall the last time something like that happened in politics or religion.
(1987) --
Carl Sagan
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