Phosgene Quotes (2 quotes)
From common salt are obtained chemically as primary derivatives chlorine—both a war gas and a means of purifying water; and 'caustic soda.' … [O]n the chlorine side there is obtained chloride of lime, (a bleaching powder and a disinfectant), chloroform (an anesthetic), phosgene (a frightful ware gas), chloroacetophenone (another war gas), and an indigo and a yellow dye. [O]n the soda side we get metallic sodium, from which are derived sodium cyanide (a disinfectant), two medicines with [long] names, another war gas, and a beautiful violet dye. Thus, from a healthful, preservative condiment come things useful and hurtful—according to the intent or purpose.
When the simplest compounds of this element are considered (marsh gas, chloride of carbon, chloroform, carbonic acid, phosgene, sulphide of carbon, hydrocyanic acid, etc.) it is seen that the quantity of carbon which chemists have recognised as the smallest possible, that is, as an atom, always unites with 4 atoms of a monatomic or with two atoms of a diatomic element; that in general, the sum of the chemical units of the elements united with one atom of carbon is 4. This leads us to the view that carbon is tetratomic or tetrabasic. In the cases of substances which contain several atoms of carbon, it must be assumed that at least some of the atoms are in some way held in the compound by the affinity of carbon, and that the carbon atoms attach themselves to one another, whereby a part of the affinity of the one is naturally engaged with an equal part of the affinity of the other. The simplest and therefore the most probable case of such an association of carbon atoms is that in which one affinity unit of one is bound by one of the other. Of the 2 x 4 affinity units of the two carbon atoms, two are used up in holding the atoms together, and six remain over, which can be bound by atom)' of other elements.