Carbon Quotes (68 quotes)
[The nanotube] brings those properties you cannot get from other organic molecules. And it’s still carbon, so it has organic chemistry. Here is an object that has, to a superlative degree, the aspects that we hold most central to the inorganic world: hardness, toughness, terrific strength, thermal and electrical conductivity. Things you just can’t do with bone and wood. But it’s made out of carbon. It’s something that plays the game at the same level of perfection as molecules and life.
[To elucidate using models] the different combining powers in elementary atoms, I … select my illustrations from that most delightful of games, croquet. Let the croquet balls represent our atoms, and let us distinguish the atoms of different elements by different colours. The white balls are hydrogen, the green ones chlorine atoms; the atoms of fiery oxygen are red, those of nitrogen, blue; the carbon atoms, lastly, are naturally represented by black balls. But we have, in addition, exhibit the different combining powers of these atoms … by screwing into the balls a number of metallic arms (tubes and pins), which correspond respectively to the combining powers of the atoms represented … to join the balls … in imitation of the atomic edifices represented.
[In refutation of evolution] They use carbon dating ... to prove that something was millions of years old. Well, we have the eruption of Mt. Saint Helens and the carbon dating test that they used then would have to then prove that these were hundreds of millions of years younger, when what happened was they had the exact same results on the fossils and canyons that they did the tests on that were supposedly 100 millions of years old. And it’s the kind of inconsistent tests like this that they’re basing their “facts” on.
[Citing results from a solitary young-Earth creationist, questioning whether the lava dome at Mount St. Helens is really a million years old.]
[Citing results from a solitary young-Earth creationist, questioning whether the lava dome at Mount St. Helens is really a million years old.]
Question: Why do the inhabitants of cold climates eat fat? How would you find experimentally the relative quantities of heat given off when equal weights of sulphur, phosphorus, and carbon are thoroughly burned?
Answer: An inhabitant of cold climates (called Frigid Zoans) eats fat principally because he can't get no lean, also because he wants to rise is temperature. But if equal weights of sulphur phosphorus and carbon are burned in his neighbourhood he will give off eating quite so much. The relative quantities of eat given off will depend upon how much sulphur etc. is burnt and how near it is burned to him. If I knew these facts it would be an easy sum to find the answer.
Answer: An inhabitant of cold climates (called Frigid Zoans) eats fat principally because he can't get no lean, also because he wants to rise is temperature. But if equal weights of sulphur phosphorus and carbon are burned in his neighbourhood he will give off eating quite so much. The relative quantities of eat given off will depend upon how much sulphur etc. is burnt and how near it is burned to him. If I knew these facts it would be an easy sum to find the answer.
1839—The fermentation satire
THE MYSTERY OF ALCOHOLIC FERMENTATION RESOLVED
(Preliminary Report by Letter) Schwindler
I am about to develop a new theory of wine fermentation … Depending on the weight, these seeds carry fermentation to completion somewhat less than as in the beginning, which is understandable … I shall develop a new theory of wine fermentation [showing] what simple means Nature employs in creating the most amazing phenomena. I owe it to the use of an excellent microscope designed by Pistorius.
When brewer’s yeast is mixed with water the microscope reveals that the yeast dissolves into endless small balls, which are scarcely 1/800th of a line in diameter … If these small balls are placed in sugar water, it can be seen that they consist of the eggs of animals. As they expand, they burst, and from them develop small creatures that multiply with unbelievable rapidity in a most unheard of way. The form of these animals differs from all of the 600 types described up until now. They possess the shape of a Beinsdorff still (without the cooling apparatus). The head of the tube is a sort of proboscis, the inside of which is filled with fine bristles 1/2000th of a line long. Teeth and eyes are not discernible; however, a stomach, intestinal canal, anus (a rose red dot), and organs for secretion of urine are plainly discernible. From the moment they are released from the egg one can see these animals swallow the sugar from the solution and pass it to the stomach. It is digested immediately, a process recognized easily by the resultant evacuation of excrements. In a word, these infusors eat sugar, evacuate ethyl alcohol from the intestinal canal, and carbon dioxide from the urinary organs. The bladder, in the filled state, has the form of a champagne bottle; when empty, it is a small button … As soon as the animals find no more sugar present, they eat each other up, which occurs through a peculiar manipulation; everything is digested down to the eggs which pass unchanged through the intestinal canal. Finally, one again fermentable yeast, namely the seed of the animals, which remain over.
THE MYSTERY OF ALCOHOLIC FERMENTATION RESOLVED
(Preliminary Report by Letter) Schwindler
I am about to develop a new theory of wine fermentation … Depending on the weight, these seeds carry fermentation to completion somewhat less than as in the beginning, which is understandable … I shall develop a new theory of wine fermentation [showing] what simple means Nature employs in creating the most amazing phenomena. I owe it to the use of an excellent microscope designed by Pistorius.
When brewer’s yeast is mixed with water the microscope reveals that the yeast dissolves into endless small balls, which are scarcely 1/800th of a line in diameter … If these small balls are placed in sugar water, it can be seen that they consist of the eggs of animals. As they expand, they burst, and from them develop small creatures that multiply with unbelievable rapidity in a most unheard of way. The form of these animals differs from all of the 600 types described up until now. They possess the shape of a Beinsdorff still (without the cooling apparatus). The head of the tube is a sort of proboscis, the inside of which is filled with fine bristles 1/2000th of a line long. Teeth and eyes are not discernible; however, a stomach, intestinal canal, anus (a rose red dot), and organs for secretion of urine are plainly discernible. From the moment they are released from the egg one can see these animals swallow the sugar from the solution and pass it to the stomach. It is digested immediately, a process recognized easily by the resultant evacuation of excrements. In a word, these infusors eat sugar, evacuate ethyl alcohol from the intestinal canal, and carbon dioxide from the urinary organs. The bladder, in the filled state, has the form of a champagne bottle; when empty, it is a small button … As soon as the animals find no more sugar present, they eat each other up, which occurs through a peculiar manipulation; everything is digested down to the eggs which pass unchanged through the intestinal canal. Finally, one again fermentable yeast, namely the seed of the animals, which remain over.
A force unconnected with matter, hovering loose over matter, is an utterly empty conception. In nitrogen, carbon, hydrogen, oxygen, in sulphur and phosphorus, their several properties have dwelt from all eternity.
A lot of people ask, “Do you think humans are parasites?” It’s an interesting idea and one worth thinking about. People casually refer to humanity as a virus spreading across the earth. In fact, we do look like some strange kind of bio-film spreading across the landscape. A good metaphor? If the biosphere is our host, we do use it up for our own benefit. We do manipulate it. We alter the flows and fluxes of elements like carbon and nitrogen to benefit ourselves—often at the expense of the biosphere as a whole. If you look at how coral reefs or tropical forests are faring these days, you’ll notice that our host is not doing that well right now. Parasites are very sophisticated; parasites are highly evolved; parasites are very successful, as reflected in their diversity. Humans are not very good parasites. Successful parasites do a very good job of balancing—using up their hosts and keeping them alive. It’s all a question of tuning the adaptation to your particular host. In our case, we have only one host, so we have to be particularly careful.
A man in twenty-four hours converts as much as seven ounces of carbon into carbonic acid; a milch cow will convert seventy ounces, and a horse seventy-nine ounces, solely by the act of respiration. That is, the horse in twenty-four hours burns seventy-nine ounces of charcoal, or carbon, in his organs of respiration to supply his natural warmth in that time ..., not in a free state, but in a state of combination.
A working definition of life, … could [be] in terms of a large molecule made up of carbon compounds that can replicate, or make copies of itself, and metabolize food and energy…: macromolecule, metabolism, replication.
Built up of carbon, hydrogen, oxygen, nitrogen, together with traces of a few other elements, yet of a complexity of structure that has hitherto resisted all attempts at complete analysis, protoplasm is at once the most enduring and the most easily destroyed of substances; its molecules are constantly breaking down to furnish the power for the manifestations of vital phenomena, and yet, through its remarkable property of assimilation, a power possessed by nothing else upon earth, it constantly builds up its substance anew from the surrounding medium.
But nothing of a nature foreign to the duties of my profession [clergyman] engaged my attention while I was at Leeds so much as the, prosecution of my experiments relating to electricity, and especially the doctrine of air. The last I was led into a consequence of inhabiting a house adjoining to a public brewery, where first amused myself with making experiments on fixed air [carbon dioxide] which found ready made in the process of fermentation. When I removed from that house, I was under the necessity making the fixed air for myself; and one experiment leading to another, as I have distinctly and faithfully noted in my various publications on the subject, I by degrees contrived a convenient apparatus for the purpose, but of the cheapest kind. When I began these experiments I knew very little of chemistry, and had in a manner no idea on the subject before I attended a course of chymical lectures delivered in the Academy at Warrington by Dr. Turner of Liverpool. But I have often thought that upon the whole, this circumstance was no disadvantage to me; as in this situation I was led to devise an apparatus and processes of my own, adapted to my peculiar views. Whereas, if I had been previously accustomed to the usual chemical processes, I should not have so easily thought of any other; and without new modes of operation I should hardly have discovered anything materially new.
By blending water and minerals from below with sunlight and CO2 from above, green plants link the earth to the sky. We tend to believe that plants grow out of the soil, but in fact most of their substance comes from the air. The bulk of the cellulose and the other organic compounds produced through photosynthesis consists of heavy carbon and oxygen atoms, which plants take directly from the air in the form of CO2. Thus the weight of a wooden log comes almost entirely from the air. When we burn a log in a fireplace, oxygen and carbon combine once more into CO2, and in the light and heat of the fire we recover part of the solar energy that went into making the wood.
Carbon has this genius of making a chemically stable two-dimensional, one-atom-thick membrane in a three-dimensional world. And that, I believe, is going to be very important in the future of chemistry and technology in general.
Carbon is, as may easily be shown and as I shall explain in greater detail later, tetrabasic or tetratomic, that is 1 atom of carbon = C = 12 is equivalent to 4 At.H. The simplest connection of C with an element of the first Group, with H or Cl for example, is therefore: CH4 and CCl4.
Chemical biodynamics, involving as it does, the fusion of many scientific disciplines, … [played a role] in the elucidation of the carbon cycle. It can be expected to take an increasingly important place in the understanding of the dynamics of living organisms on a molecular level.
Chemical signs ought to be letters, for the greater facility of writing, and not to disfigure a printed book ... I shall take therefore for the chemical sign, the initial letter of the Latin name of each elementary substance: but as several have the same initial letter, I shall distinguish them in the following manner:— 1. In the class which I shall call metalloids, I shall employ the initial letter only, even when this letter is common to the metalloid and to some metal. 2. In the class of metals, I shall distinguish those that have the same initials with another metal, or a metalloid, by writing the first two letters of the word. 3. If the first two letters be common to two metals, I shall, in that case, add to the initial letter the first consonant which they have not in common: for example, S = sulphur, Si = silicium, St = stibium (antimony), Sn = stannum (tin), C = carbonicum, Co = colbaltum (colbalt), Cu = cuprum (copper), O = oxygen, Os = osmium, &c.
Chemistry dissolves the goddess in the alembic,
Venus, the white queen, the universal matrix,
Down to the molecular hexagons and carbon-chains.
Venus, the white queen, the universal matrix,
Down to the molecular hexagons and carbon-chains.
Each of us has read somewhere that in New Guinea pidgin the word for 'piano' is (I use English spelling) 'this fellow you hit teeth belonging to him he squeal all same pig'. I am inclined to doubt whether this expression is authentic; it looks just like the kind of thing a visitor to the Islands would facetiously invent. But I accept 'cut grass belong head belong me' for 'haircut' as genuine... Such phrases seem very funny to us, and make us feel very superior to the ignorant foreigners who use long winded expressions for simple matters. And then it is our turn to name quite a simple thing, a small uncomplicated molecule consisting of nothing more than a measly 11 carbons, seven hydrogens, one nitrogen and six oxygens. We sharpen our pencils, consult our rule books and at last come up with 3-[(1, 3- dihydro-1, 3-dioxo-2H-isoindol-2-yl) oxy]-3-oxopropanoic acid. A name like that could drive any self-respecting Papuan to piano-playing.
Finally I got to carbon, and as you all know, in the case of carbon the reaction works out beautifully. One goes through six reactions, and at the end one comes back to carbon. In the process one has made four hydrogen atoms into one of helium. The theory, of course, was not made on the railway train from Washington to Ithaca … It didn’t take very long, it took about six weeks, but not even the Trans-Siberian railroad [has] taken that long for its journey.
Food is at present obtained almost entirely from the energy of the sunlight. The radiation from the sun produces from the carbonic acid in the air more or less complicated carbon compounds which serve us in plants and vegetables. We use the latent chemical energy of these to keep our bodies warm, we convert it into muscular effort. We employ it in the complicated process of digestion to repair and replace the wasted cells of our bodies. … If the gigantic sources of power become available, food would be produced without recourse to sunlight. Vast cellars, in which artificial radiation is generated, may replace the cornfields and potato patches of the world.
Food production is now so energy-intensive that more carbon is emitted providing a person with enough calories to walk to the shops than a car would emit over the same distance.
Citing calculations made by environmentalist author, Chris Goodall.
Citing calculations made by environmentalist author, Chris Goodall.
Forests are a fundamental component of our planet’s recovery. They are the best technology nature has for locking away carbon. And they are centers of biodiversity. Again, the two features work together. The wilder and more diverse forests are, the more effective they are at absorbing carbon from the atmosphere
Four elements, hydrogen, carbon, oxygen and nitrogen, also provide an example of the astonishing togetherness of our universe. They make up the “organic” molecules that constitute living organisms on a planet, and the nuclei of these same elements interact to generate the light of its star. Then the organisms on the planet come to depend wholly on that starlight, as they must if life is to persist. So it is that all life on the Earth runs on sunlight. [Referring to photosynthesis]
I should like to call the number of atom groups, with which an elementary atom coordinates … to form a complex radical, the coordination number of the atom in question … We must differentiate between valence number and coordination number. The valence number indicates the maximum number of monovalent atoms which can be bound directly to the atom in question without the participation of other elementary atoms … Perhaps this concept [of coordination number] is destined to serve as a basis for the theory of the constitution of inorganic compounds, just as valence theory formed the basis for the constitutional theory of carbon compounds.
I tell my students, with a feeling of pride that I hope they will share, that the carbon, nitrogen, and oxygen that make up ninety-nine per cent of our living substance were cooked in the deep interiors of earlier generations of dying stars. Gathered up from the ends of the universe, over billions of years, eventually they came to form, in part, the substance of our sun, its planets, and ourselves. Three billion years ago, life arose upon the earth. It is the only life in the solar system.
I try to identify myself with the atoms ... I ask what I would do If I were a carbon atom or a sodium atom.
I was sitting writing at my textbook but the work did not progress; my thoughts were elsewhere. I turned my chair to the fire and dozed. Again the atoms were gambolling before my eyes. This time the smaller groups kept modestly in the background. My mental eye, rendered more acute by the repeated visions of the kind, could now distinguish larger structures of manifold confirmation: long rows, sometimes more closely fitted together all twining and twisting in snake like motion. But look! What was that? One of the snakes had seized hold of its own tail, and the form whirled mockingly before my eyes. As if by a flash of lightning I awoke; and this time also I spent the rest of the night in working out the rest of the hypothesis. Let us learn to dream, gentlemen, then perhaps we shall find the truth... But let us beware of publishing our dreams till they have been tested by waking understanding.
I’m sick of people thinking that efficiency is going to be sufficient. I’m sick of seeing people say, “I’m going to reduce my carbon footprint,” and think that being less bad is being good. … I want healthy, safe things in closed cycles, not just being less bad.
If we wish to give an account of the atomic constitution of the aromatic compounds, we are bound to explain the following facts:
1) All aromatic compounds, even the most simple, are relatively richer in carbon than the corresponding compounds in the class of fatty bodies.
2) Among the aromatic compounds, as well as among the fatty bodies, a large number of homologous substances exist.
3) The most simple aromatic compounds contain at least six atoms of carbon.
4) All the derivatives of aromatic substances exhibit a certain family likeness; they all belong to the group of 'Aromatic compounds'. In cases where more vigorous reactions take place, a portion of the carbon is often eliminated, but the chief product contains at least six atoms of carbon These facts justify the supposition that all aromatic compounds contain a common group, or, we may say, a common nucleus consisting of six atoms of carbon. Within this nucleus a more intimate combination of the carbon atoms takes place; they are more compactly placed together, and this is the cause of the aromatic bodies being relatively rich in carbon. Other carbon atoms can be joined to this nucleus in the same way, and according to the same law, as in the case of the group of fatty bodies, and in this way the existence of homologous compounds is explained.
1) All aromatic compounds, even the most simple, are relatively richer in carbon than the corresponding compounds in the class of fatty bodies.
2) Among the aromatic compounds, as well as among the fatty bodies, a large number of homologous substances exist.
3) The most simple aromatic compounds contain at least six atoms of carbon.
4) All the derivatives of aromatic substances exhibit a certain family likeness; they all belong to the group of 'Aromatic compounds'. In cases where more vigorous reactions take place, a portion of the carbon is often eliminated, but the chief product contains at least six atoms of carbon These facts justify the supposition that all aromatic compounds contain a common group, or, we may say, a common nucleus consisting of six atoms of carbon. Within this nucleus a more intimate combination of the carbon atoms takes place; they are more compactly placed together, and this is the cause of the aromatic bodies being relatively rich in carbon. Other carbon atoms can be joined to this nucleus in the same way, and according to the same law, as in the case of the group of fatty bodies, and in this way the existence of homologous compounds is explained.
If you look at a tree and think of it as a design assignment, it would be like asking you to make something that makes oxygen, sequesters carbon, fixes nitrogen, distills water, provides habitat for hundreds of species, accrues solar energy’s fuel, makes complex sugars and food, changes colors with the seasons, creates microclimates, and self-replicates.
In experimenting on the arc, my aim was not so much to add to the large number of isolated facts that had already been discovered, as to form some idea of the bearing of these upon one another, and thus to arrive at a clear conception of what takes place in each part of the arc and carbons at every moment. The attempt to correlate all the known phenomena, and to bind them together into one consistent whole, led to the deduction of new facts, which, when duly tested by experiment, became parts of the growing body, and, themselves, opened up fresh questions, to be answered in their turn by experiment.
In fact, the thickness of the Earth's atmosphere, compared with the size of the Earth, is in about the same ratio as the thickness of a coat of shellac on a schoolroom globe is to the diameter of the globe. That's the air that nurtures us and almost all other life on Earth, that protects us from deadly ultraviolet light from the sun, that through the greenhouse effect brings the surface temperature above the freezing point. (Without the greenhouse effect, the entire Earth would plunge below the freezing point of water and we'd all be dead.) Now that atmosphere, so thin and fragile, is under assault by our technology. We are pumping all kinds of stuff into it. You know about the concern that chlorofluorocarbons are depleting the ozone layer; and that carbon dioxide and methane and other greenhouse gases are producing global warming, a steady trend amidst fluctuations produced by volcanic eruptions and other sources. Who knows what other challenges we are posing to this vulnerable layer of air that we haven't been wise enough to foresee?
In Melvin Calvin’s office there were four photographs: Michael Polanyi, Joel Hildebrand, Gilbert N. Lewis, and Ernest O. Lawrence. These scientists were his mentors: Polanyi for introducing him to the chemistry of phthalocyanine; Hildebrand for bringing him to Berkeley; Lewis, perhaps his most influential teacher; and Lawrence, who provided him the opportunity to work with the new scientific tool of radioactive carbon, which enabled the search for the path of carbon in photosynthesis to be successful.
Incandescent carbon particles, by the tens of millions, leap free of the log and wave like banners, as flame. Several hundred significantly different chemical reactions are now going on. For example, a carbon atom and four hydrogen atoms, coming out of the breaking cellulose, may lock together and form methane, natural gas. The methane, burning (combining with oxygen), turns into carbon dioxide and water, which also go up the flue. If two carbon atoms happen to come out of the wood with six hydrogen atoms, they are, agglomerately, ethane, which bums to become, also, carbon dioxide and water. Three carbons and eight hydrogens form propane, and propane is there, too, in the fire. Four carbons and ten hydrogens—butane. Five carbons … pentane. Six … hexane. Seven … heptane. Eight carbons and eighteen hydrogens—octane. All these compounds come away in the breaking of the cellulose molecule, and burn, and go up the chimney as carbon dioxide and water. Pentane, hexane, heptane, and octane have a collective name. Logs burning in a fireplace are making and burning gasoline.
It is possible with … carbon … to form very large molecules that are stable. This results from the stability of the carbon-to-carbon bond. You must have complexity in order to achieve the versatility characteristic of living organisms. You can achieve this complexity with carbon forming the molecular backbone.
It is the destiny of wine to be drunk, and it is the destiny of glucose to be oxidized. But it was not oxidized immediately: its drinker kept it in his liver for more than a week, well curled up and tranquil, as a reserve aliment for a sudden effort; an effort that he was forced to make the following Sunday, pursuing a bolting horse. Farewell to the hexagonal structure: in the space of a few instants the skein was unwound and became glucose again, and this was dragged by the bloodstream all the way to a minute muscle fiber in the thigh, and here brutally split into two molecules of lactic acid, the grim harbinger of fatigue: only later, some minutes after, the panting of the lungs was able to supply the oxygen necessary to quietly oxidize the latter. So a new molecule of carbon dioxide returned to the atmosphere, and a parcel of the energy that the sun had handed to the vine-shoot passed from the state of chemical energy to that of mechanical energy, and thereafter settled down in the slothful condition of heat, warming up imperceptibly the air moved by the running and the blood of the runner. 'Such is life,' although rarely is it described in this manner: an inserting itself, a drawing off to its advantage, a parasitizing of the downward course of energy, from its noble solar form to the degraded one of low-temperature heat. In this downward course, which leads to equilibrium and thus death, life draws a bend and nests in it.
It was found after many troublesome experiments that when the vacuum within the lamp globe was good, and the contact between the carbon and the conductor which supported it sufficient, there was no blackening of the globes, and no appreciable wasting away of the carbons. Thus was swept away a pernicious error, which, like a misleading finger post proclaiming “No road this way,” tended to bar progress along a good thoroughfare. It only remained to perfect the details of the lamp, to find the best material from which to form the carbon, and to fix this material in the lamp in the best manner. These points, I think, I have now satisfactorily settled, and you see the result in the lamp before me on the table.
Judging from our experience upon this planet, such a history, that begins with elementary particles, leads perhaps inevitably toward a strange and moving end: a creature that knows, a science-making animal, that turns back upon the process that generated him and attempts to understand it. Without his like, the universe could be, but not be known, and this is a poor thing. Surely this is a great part of our dignity as men, that we can know, and that through us matter can know itself; that beginning with protons and electrons, out of the womb of time and the vastnesses of space, we can begin to understand; that organized as in us, the hydrogen, the carbon, the nitrogen, the oxygen, those 16-21 elements, the water, the sunlight—all having become us, can begin to understand what they are, and how they came to be.
Krill, a vital food sources for sea life, is being snatched in vast quantities, with trawlers traveling halfway around the globe, generating ruinous carbon emissions in the form of global supply chains.
Life exists in the universe only because the carbon atom possesses certain exceptional properties.
My attitude was: “Just look at all the interesting atoms in that region of the periodic table; certainly the reason that carbon dominates chemistry is our own ignorance.”
Once you ask the question, where is the Carbon-14, and where does it go, it’s like one, two, three, you have [radiocarbon] dating.
One wintry night, dozing by firelight,
Kekulé dreamt of snakes curling tight,
With whirl and twist,
In a scholarly tryst,
Carbon’s ring structure burst clearly in sight.
Kekulé dreamt of snakes curling tight,
With whirl and twist,
In a scholarly tryst,
Carbon’s ring structure burst clearly in sight.
Organic chemistry is the chemistry of carbon compounds. Biochemistry is the study of carbon compounds that crawl.
Our atom of carbon enters the leaf, colliding with other innumerable (but here useless) molecules of nitrogen and oxygen. It adheres to a large and complicated molecule that activates it, and simultaneously receives the decisive message from the sky, in the flashing form of a packet of solar light; in an instant, like an insect caught by a spider, it is separated from its oxygen, combined with hydrogen and (one thinks) phosphorus, and finally inserted in a chain, whether long or short does not matter, but it is the chain of life. All this happens swiftly, in silence, at the temperature and pressure of the atmosphere, and gratis: dear colleagues, when we learn to do likewise we will be sicut Deus [like God], and we will have also solved the problem of hunger in the world.
She [Rosalind Franklin] discovered in a series of beautifully executed researches the fundamental distinction between carbons that turned on heating into graphite and those that did not. Further she related this difference to the chemical constitution of the molecules from which carbon was made. She was already a recognized authority in industrial physico-chemistry when she chose to abandon this work in favour of the far more difficult and more exciting fields of biophysics.
Soccer ball C60 quickly became a sort of “Rosetta Stone” leading to the discovery of a new world of geodesic structures of pure carbon built on the nanometer scale.
The absorption of oxygen and the elimination of carbon dioxide in the lungs take place by diffusion alone. There is no trustworthy evidence of any regulation of this process on the part of the organism.
The carbon output that melts the ice in the Arctic also causes ocean acidification, which results from the ocean absorbing excess carbon dioxide from the atmosphere (the same carbon dioxide that is the primary cause of global warming, hence the nickname “the other carbon problem”).
The discovery of an interaction among the four hemes made it obvious that they must be touching, but in science what is obvious is not necessarily true. When the structure of hemoglobin was finally solved, the hemes were found to lie in isolated pockets on the surface of the subunits. Without contact between them how could one of them sense whether the others had combined with oxygen? And how could as heterogeneous a collection of chemical agents as protons, chloride ions, carbon dioxide, and diphosphoglycerate influence the oxygen equilibrium curve in a similar way? It did not seem plausible that any of them could bind directly to the hemes or that all of them could bind at any other common site, although there again it turned out we were wrong. To add to the mystery, none of these agents affected the oxygen equilibrium of myoglobin or of isolated subunits of hemoglobin. We now know that all the cooperative effects disappear if the hemoglobin molecule is merely split in half, but this vital clue was missed. Like Agatha Christie, Nature kept it to the last to make the story more exciting. There are two ways out of an impasse in science: to experiment or to think. By temperament, perhaps, I experimented, whereas Jacques Monod thought.
The explosions [of dying stars] scattered the heavy elements as a fine dust through space. By the time it made the Sun, the primordial gas of the Milky Way was sufficiently enriched with heavier elements for rocky planets like the Earth to form. And from the rocks atoms escaped for eventual incorporation in living things: carbon, nitrogen, oxygen, phosphorus and sulphur for all living tissue; calcium for bones and teeth; sodium and potassium for the workings of nerves and brains; the iron colouring blood red… and so on.
No other conclusion of modern research testifies more clearly to mankind’s intimate connections with the universe at large and with the cosmic forces at work among the stars.
The nitrogen in our DNA, the calcium in our teeth, the iron in our blood, the carbon in our apple pies were made in the interiors of collapsing stars. We are made of starstuff.
The world's forests need to be seen for what they are—giant global utilities, providing essential public services to humanity on a vast scale. They store carbon, which is lost to the atmosphere when they burn, increasing global warming. The life they support cleans the atmosphere of pollutants and feeds it with moisture. They act as a natural thermostat, helping to regulate our climate and sustain the lives of 1.4 billion of the poorest people on this Earth. And they do these things to a degree that is all but impossible to imagine.
There's antimony, arsenic, aluminium, selenium,
And hydrogen and oxygen and nitrogen and rhenium,
And nickel, neodymium, neptunium, germanium,
And iron, americium, ruthenium, uranium,
Europium, zirconium, lutetium, vanadium,
And lanthanum and osmium and astatine and radium,
And gold and protactinium and indium and gallium,
And iodine and thorium and thulium and thallium.
There's yttrium, ytterbium, actinium, rubidium,
And boron, gadolinium, niobium, iridium,
And strontium and silicon and silver and samarium,
And bismuth, bromine, lithium, beryllium and barium.
There's holmium and helium and hafnium and erbium,
And phosphorus and francium and fluorine and terbium,
And manganese and mercury, molybdenum, magnesium,
Dysprosium and scandium and cerium and cesium,
And lead, praseodymium and platinum, plutonium,
Palladium, promethium, potassium, polonium,
And tantalum, technetium, titanium, tellurium,
And cadmium and calcium and chromium and curium.
There's sulfur, californium and fermium, berkelium,
And also mendelevium, einsteinium, nobelium,
And argon, krypton, neon, radon, xenon, zinc and rhodium,
And chlorine, cobalt, carbon, copper, tungsten, tin and sodium.
These are the only ones of which the news has come to Harvard,
And there may be many others, but they haven't been discarvard.
[To the tune of I am the Very Model of a Modern Major General.]
And hydrogen and oxygen and nitrogen and rhenium,
And nickel, neodymium, neptunium, germanium,
And iron, americium, ruthenium, uranium,
Europium, zirconium, lutetium, vanadium,
And lanthanum and osmium and astatine and radium,
And gold and protactinium and indium and gallium,
And iodine and thorium and thulium and thallium.
There's yttrium, ytterbium, actinium, rubidium,
And boron, gadolinium, niobium, iridium,
And strontium and silicon and silver and samarium,
And bismuth, bromine, lithium, beryllium and barium.
There's holmium and helium and hafnium and erbium,
And phosphorus and francium and fluorine and terbium,
And manganese and mercury, molybdenum, magnesium,
Dysprosium and scandium and cerium and cesium,
And lead, praseodymium and platinum, plutonium,
Palladium, promethium, potassium, polonium,
And tantalum, technetium, titanium, tellurium,
And cadmium and calcium and chromium and curium.
There's sulfur, californium and fermium, berkelium,
And also mendelevium, einsteinium, nobelium,
And argon, krypton, neon, radon, xenon, zinc and rhodium,
And chlorine, cobalt, carbon, copper, tungsten, tin and sodium.
These are the only ones of which the news has come to Harvard,
And there may be many others, but they haven't been discarvard.
[To the tune of I am the Very Model of a Modern Major General.]
This discovery [of fullerenes] is principally about the way that carbon condenses, it’s genius for forming clusters.
Those of us who were familiar with the state of inorganic chemistry in universities twenty to thirty years ago will recall that at that time it was widely regarded as a dull and uninteresting part of the undergraduate course. Usually, it was taught almost entirely in the early years of the course and then chiefly as a collection of largely unconnected facts. On the whole, students concluded that, apart from some relationships dependent upon the Periodic table, there was no system in inorganic chemistry comparable with that to be found in organic chemistry, and none of the rigour and logic which characterised physical chemistry. It was widely believed that the opportunities for research in inorganic chemistry were few, and that in any case the problems were dull and uninspiring; as a result, relatively few people specialized in the subject... So long as inorganic chemistry is regarded as, in years gone by, as consisting simply of the preparations and analysis of elements and compounds, its lack of appeal is only to be expected. The stage is now past and for the purpose of our discussion we shall define inorganic chemistry today as the integrated study of the formation, composition, structure and reactions of the chemical elements and compounds, excepting most of those of carbon.
To day we made the grand experiment of burning the diamond and certainly the phenomena presented were extremely beautiful and interesting… The Duke’s burning glass was the instrument used to apply heat to the diamond. It consists of two double convex lenses … The instrument was placed in an upper room of the museum and having arranged it at the window the diamond was placed in the focus and anxiously watched. The heat was thus continued for 3/4 of an hour (it being necessary to cool the globe at times) and during that time it was thought that the diamond was slowly diminishing and becoming opaque … On a sudden Sir H Davy observed the diamond to burn visibly, and when removed from the focus it was found to be in a state of active and rapid combustion. The diamond glowed brilliantly with a scarlet light, inclining to purple and, when placed in the dark, continued to burn for about four minutes. After cooling the glass heat was again applied to the diamond and it burned again though not for nearly so long as before. This was repeated twice more and soon after the diamond became all consumed. This phenomenon of actual and vivid combustion, which has never been observed before, was attributed by Sir H Davy to be the free access of air; it became more dull as carbonic acid gas formed and did not last so long.
We cannot hope to either understand or to manage the carbon in the atmosphere unless we understand and manage the trees and the soil too.
We define organic chemistry as the chemistry of carbon compounds.
We need to be realistic. There is very little we can do now to stop the ice from disappearing from the North Pole in the Summer. And we probably cannot prevent the melting of the permafrost and the resulting release of methane. In addition, I fear that we may be too late to help the oceans maintain their ability to absorb carbon dioxide. But there is something we can do—and it could make the whole difference and buy us time to develop the necessary low carbon economies. We can halt the destruction of the world’s rainforests—and even restore parts of them—in order to ensure that the forests do what they are so good at—in other words storing carbon naturally. This is a far easier, cheaper and quicker option than imagining we can rely on as yet unproven technology to capture carbon at a cost of some $50 per tonne or, for that matter, imagining we can achieve what is necessary through plantation timber.
We need to think of “blue carbon” and other services provided by healthy marine ecosystems. Mangroves, seagrasses and coastal marshes are great sinks for atmospheric carbon.
When carbon (C), Oxygen (o) and hydrogen (H) atoms bond in a certain way to form sugar, the resulting compound has a sweet taste. The sweetness resides neither in the C, nor in the O, nor in the H; it resides in the pattern that emerges from their interaction. It is an emergent property. Moreover, strictly speaking, is not a property of the chemical bonds. It is a sensory experience that arises when the sugar molecules interact with the chemistry of our taste buds, which in turns causes a set of neurons to fire in a certain way. The experience of sweetness emerges from that neural activity.
When the simplest compounds of this element are considered (marsh gas, chloride of carbon, chloroform, carbonic acid, phosgene, sulphide of carbon, hydrocyanic acid, etc.) it is seen that the quantity of carbon which chemists have recognised as the smallest possible, that is, as an atom, always unites with 4 atoms of a monatomic or with two atoms of a diatomic element; that in general, the sum of the chemical units of the elements united with one atom of carbon is 4. This leads us to the view that carbon is tetratomic or tetrabasic. In the cases of substances which contain several atoms of carbon, it must be assumed that at least some of the atoms are in some way held in the compound by the affinity of carbon, and that the carbon atoms attach themselves to one another, whereby a part of the affinity of the one is naturally engaged with an equal part of the affinity of the other. The simplest and therefore the most probable case of such an association of carbon atoms is that in which one affinity unit of one is bound by one of the other. Of the 2 x 4 affinity units of the two carbon atoms, two are used up in holding the atoms together, and six remain over, which can be bound by atom)' of other elements.
When the state is shaken to its foundations by internal or external events, when commerce, industry and all trades shall be at a stand, and perhaps on the brink of ruin; when the property and fortune of all are shaken or changed, and the inhabitants of towns look forward with dread and apprehension to the future, then the agriculturalist holds in his hand the key to the money chest of the rich, and the savings-box of the poor; for political events have not the slightest influence on the natural law, which forces man to take into his system, daily, a certain number of ounces of carbon and nitrogen.
Reflecting on events of 1848.
Reflecting on events of 1848.
When ultra-violet light acts on a mixture of water, carbon dioxide, and ammonia, a vast variety of organic substances are made, including sugars and apparently some of the materials from which proteins are built up…. But before the origin of life they must have accumulated till the primitive oceans reached the consistency of hot dilute soup…. The first living or half-living things were probably large molecules synthesized under the influence of the sun’s radiation, and only capable of reproduction in the particularly favorable medium in which they originated….
You can’t see oxygen being generated by trees, carbon dioxide being taken up by trees, but we get that. We’re beginning to understand the importance of forests. But the ocean has its forests, too. They just happen to be very small. They’re very small in size but they’re very large in numbers.
You will be astonished when I tell you what this curious play of carbon amounts to. A candle will burn some four, five, six, or seven hours. What, then, must be the daily amount of carbon going up into the air in the way of carbonic acid! ... Then what becomes of it? Wonderful is it to find that the change produced by respiration ... is the very life and support of plants and vegetables that grow upon the surface of the earth.
You will die but the carbon will not; its career does not end with you. It will return to the soil, and there a plant may take it up again in time, sending it once more on a cycle of plant and animal life.