Spectral Line Quotes (5 quotes)
After the discovery of spectral analysis no one trained in physics could doubt the problem of the atom would be solved when physicists had learned to understand the language of spectra. So manifold was the enormous amount of material that has been accumulated in sixty years of spectroscopic research that it seemed at first beyond the possibility of disentanglement. An almost greater enlightenment has resulted from the seven years of Rφntgen spectroscopy, inasmuch as it has attacked the problem of the atom at its very root, and illuminates the interior. What we are nowadays hearing of the language of spectra is a true 'music of the spheres' in order and harmony that becomes ever more perfect in spite of the manifold variety. The theory of spectral lines will bear the name of Bohr for all time. But yet another name will be permanently associated with it, that of Planck. All integral laws of spectral lines and of atomic theory spring originally from the quantum theory. It is the mysterious organon on which Nature plays her music of the spectra, and according to the rhythm of which she regulates the structure of the atoms and nuclei.
I had observed that there were different lines exhibited in the spectra of different metals when ignited in the voltaic arc; and if I had had any reasonable amount of wit I ought to have seen the converse, viz., that by ignition different bodies show in their spectral lines the materials of which they are formed. If that thought had occured to my mind, I should have discovered the spectroscope before Kirchoff; but it didnt.
In August, 1896, I exposed the sodium flame to large magnetic forces by placing it between the poles of a strong electromagnet. Again I studied the radiation of the flame by means of Rowland's mirror, the observations being made in the direction perpendicular to the lines of force. Each line, which in the absence of the effect of the magnetic forces was very sharply defined, was now broadened. This indicated that not only the original oscillations, but also others with greater and again others with smaller periods of oscillation were being radiated by the flame. The change was however very small. In an easily produced magnetic field it corresponded to a thirtieth of the distance between the two sodium lines, say two tenths of an Angstrom, a unit of measure whose name will always recall to physicists the meritorious work done by the father of my esteemed colleague.
It might interest you that when we made the experiments that we did not read the literature well enoughand you know how that happens. On the other hand, one would think that other people would have told us about it. For instance, we had a colloquium at the time in Berlin at which all the important papers were discussed. Nobody discussed Bohrs paper. Why not? The reason is that fifty years ago one was so convinced that nobody would, with the state of knowledge we had at that time, understand spectral line emission, so that if somebody published a paper about it, one assumed probably it is not right. So we did not know it.
The generalized theory of relativity has furnished still more remarkable results. This considers not only uniform but also accelerated motion. In particular, it is based on the impossibility of distinguishing an acceleration from the gravitation or other force which produces it. Three consequences of the theory may be mentioned of which two have been confirmed while the third is still on trial: (1) It gives a correct explanation of the residual motion of forty-three seconds of arc per century of the perihelion of Mercury. (2) It predicts the deviation which a ray of light from a star should experience on passing near a large gravitating body, the sun, namely, 1".7. On Newton's corpuscular theory this should be only half as great. As a result of the measurements of the photographs of the eclipse of 1921 the number found was much nearer to the prediction of Einstein, and was inversely proportional to the distance from the center of the sun, in further confirmation of the theory. (3) The theory predicts a displacement of the solar spectral lines, and it seems that this prediction is also verified.