Reagent Quotes (8 quotes)
Reagents Quotes
Reagents Quotes
Chemistry is one of those branches of human knowledge which has built itself upon methods and instruments by which truth can presumably be determined. It has survived and grown because all its precepts and principles can be re-tested at any time and anywhere. So long as it remained the mysterious alchemy by which a few devotees, by devious and dubious means, presumed to change baser metals into gold, it did not flourish, but when it dealt with the fact that 56 g. of fine iron, when heated with 32 g. of flowers of sulfur, generated extra heat and gave exactly 88 g. of an entirely new substance, then additional steps could be taken by anyone. Scientific research in chemistry, since the birth of the balance and the thermometer, has been a steady growth of test and observation. It has disclosed a finite number of elementary reagents composing an infinite universe, and it is devoted to their inter-reaction for the benefit of mankind.
Address upon receiving the Perkin Medal Award, 'The Big Things in Chemistry', The Journal of Industrial and Engineering Chemistry (Feb 1921), 13, No. 2, 163.
For the evolution of science by societies the main requisite is the perfect freedom of communication between each member and anyone of the others who may act as a reagent.
The gaseous condition is exemplified in the soiree, where the members rush about confusedly, and the only communication is during a collision, which in some instances may be prolonged by button-holing.
The opposite condition, the crystalline, is shown in the lecture, where the members sit in rows, while science flows in an uninterrupted stream from a source which we take as the origin. This is radiation of science. Conduction takes place along the series of members seated round a dinner table, and fixed there for several hours, with flowers in the middle to prevent any cross currents.
The condition most favourable to life is an intermediate plastic or colloidal condition, where the order of business is (1) Greetings and confused talk; (2) A short communication from one who has something to say and to show; (3) Remarks on the communication addressed to the Chair, introducing matters irrelevant to the communication but interesting to the members; (4) This lets each member see who is interested in his special hobby, and who is likely to help him; and leads to (5) Confused conversation and examination of objects on the table.
I have not indicated how this programme is to be combined with eating.
The gaseous condition is exemplified in the soiree, where the members rush about confusedly, and the only communication is during a collision, which in some instances may be prolonged by button-holing.
The opposite condition, the crystalline, is shown in the lecture, where the members sit in rows, while science flows in an uninterrupted stream from a source which we take as the origin. This is radiation of science. Conduction takes place along the series of members seated round a dinner table, and fixed there for several hours, with flowers in the middle to prevent any cross currents.
The condition most favourable to life is an intermediate plastic or colloidal condition, where the order of business is (1) Greetings and confused talk; (2) A short communication from one who has something to say and to show; (3) Remarks on the communication addressed to the Chair, introducing matters irrelevant to the communication but interesting to the members; (4) This lets each member see who is interested in his special hobby, and who is likely to help him; and leads to (5) Confused conversation and examination of objects on the table.
I have not indicated how this programme is to be combined with eating.
Letter to William Grylls Adams (3 Dec 1873). In P. M. Harman (ed.), The Scientific Letters and Papers of James Clerk Maxwell (1995), Vol. 2, 1862-1873, 949-50.
I went to the trash pile at Tuskegee Institute and started my laboratory with bottles, old fruit jars and any other thing I found I could use. … [The early efforts were] worked out almost wholly on top of my flat topped writing desk and with teacups, glasses, bottles and reagents I made myself.
Manuscript fragment, no date, Box 1, George Washington Carver Papers. Cited in Linda O. McMurry, George Washington Carver, Scientist and Symbol (1982), 130.
In the case of chemical investigations known as decompositions or analyses, it is first important to determine exactly what ingredients you are dealing with, or chemically speaking, what substances are contained in a given mixture or composite. For this purpose we use reagents, i.e., substances that possess certain properties and characteristics, which we well know from references or personal experience, such that the changes which they bring about or undergo, so to say the language that they speak thereby inform the researcher that this or that specific substance is present in the mixture in question.
From Zur Farben-Chemie Musterbilder für Freunde des Schönen und zum Gebrauch für Zeichner, Maler, Verzierer und Zeugdrucker [On Colour Chemistry...] (1850), Introduction. Translation tweaked by Webmaster from version in Herbert and W. Roesky and Klaud Möckel, translated by T.N. Mitchell and W.E. Russey, Chemical Curiosities: Spectacular Experiments and Inspired Quotes (1996), 1. From the original German, “Bei solchen chemischen Untersuchungen, die man zersetzende oder zergliedernde nennt, kommt es zunächst darauf an, zu ermitteln, mit welchen Stoffen man es zu thun hat, oder um chemisch zu reden, welche Stoffe in einem bestimmten Gemenge oder Gemisch enthalten sind. Hierzu bedient man sich sogenannter gegenwirkender Mittel, d. h. Stoffe, die bestimmte Eigenschaften und Eigenthümlichkeiten besitzen und die man aus Ueberlieferung oder eigner Erfahrung genau kennt, so daß die Veränderungen, welche sie bewirken oder erleiden, gleichsam die Sprache sind, mit der sie reden und dadurch dem Forscher anzeigen, daß der und der bestimmte Stoff in der fraglichen Mischung enthalten sei.”
Reagents are regarded as acting by virtue of a constitutional affinity either for electrons or for nuclei... the terms electrophilic (electron-seeking) and nucleophilic (nucleus-seeking) are suggested... and the organic molecule, in the activation necessary for reaction, is therefore required to develop at the seat of attack either a high or low electron density as the case may be.
'Significance of Tautomerism and of the Reactions of Aromatic Compounds in the Electronic Theory of Organic Relations', Journal of the Chemical Society (1933), 136, 1121, fn.
Since it is proposed to regard chemical reactions as electrical transactions in which reagents act by reason of a constitutional affinity either for electrons or for atomic nuclei, it is important to be able to recognize which type of reactivity any given reagent exhibits.
'Principles of an Electronic Theory of Organic Reactions', Chemical Reviews (1934), 15, 265.
The digestive canal is in its task a complete chemical factory. The raw material passes through a long series of institutions in which it is subjected to certain mechanical and, mainly, chemical processing, and then, through innumerable side-streets, it is brought into the depot of the body. Aside from this basic series of institutions, along which the raw material moves, there is a series of lateral chemical manufactories, which prepare certain reagents for the appropriate processing of the raw material.
Speech to the Society of Russian Physicians (Dec 1874). as translated in Daniel P. Todes, Pavlov’s Physiology Factory: Experiment, Interpretation, Laboratory Enterprise (2002), 155.
When the old and bewhiskered alchemist mentally planned his transmutations from lead to gold, he no doubt considered his reagent “spiritus vitroli” second only to his trusty Philosopher’s Stone in power and usefulness; for we read of sulphuric acid back through Alchemical times.
Co-author with E.L. Larison, American Sulphuric Acid Practice (1921), 1.