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James Clerk Maxwell
(13 Jun 1831 - 5 Nov 1879)
Scottish mathematician and physicist whose researches united electricity and magnetism into the concept of the electro-magnetic field.
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James Clerk Maxwell Quotes on Law (12 quotes)
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>> Click for 53 Science Quotes by James Clerk Maxwell
>> Click for James Clerk Maxwell Quotes on | Atom | Energy | Equation | Experiment | Gas | Light | Matter | Molecule | Poem | Science | Symbol | Theory | Vibration |
A strict materialist believes that everything depends on the motion of matter. He knows the form of the laws of motion though he does not know all their consequences when applied to systems of unknown complexity.
Now one thing in which the materialist (fortified with dynamical knowledge) believes is that if every motion great & small were accurately reversed, and the world left to itself again, everything would happen backwards the fresh water would collect out of the sea and run up the rivers and finally fly up to the clouds in drops which would extract heat from the air and evaporate and afterwards in condensing would shoot out rays of light to the sun and so on. Of course all living things would regrede from the grave to the cradle and we should have a memory of the future but not of the past.
The reason why we do not expect anything of this kind to take place at any time is our experience of irreversible processes, all of one kind, and this leads to the doctrine of a beginning & an end instead of cyclical progression for ever.
Now one thing in which the materialist (fortified with dynamical knowledge) believes is that if every motion great & small were accurately reversed, and the world left to itself again, everything would happen backwards the fresh water would collect out of the sea and run up the rivers and finally fly up to the clouds in drops which would extract heat from the air and evaporate and afterwards in condensing would shoot out rays of light to the sun and so on. Of course all living things would regrede from the grave to the cradle and we should have a memory of the future but not of the past.
The reason why we do not expect anything of this kind to take place at any time is our experience of irreversible processes, all of one kind, and this leads to the doctrine of a beginning & an end instead of cyclical progression for ever.
— James Clerk Maxwell
Letter to Mark Pattison (7 Apr 1868). In P. M. Hannan (ed.), The Scientific Letters and Papers of James Clerk Maxwell (1995), Vol. 2, 1862-1873, 360-1.
Accordingly, we find Euler and D'Alembert devoting their talent and their patience to the establishment of the laws of rotation of the solid bodies. Lagrange has incorporated his own analysis of the problem with his general treatment of mechanics, and since his time M. Poinsôt has brought the subject under the power of a more searching analysis than that of the calculus, in which ideas take the place of symbols, and intelligent propositions supersede equations.
— James Clerk Maxwell
J. C. Maxwell on Louis Poinsôt (1777-1859) in 'On a Dynamical Top' (1857). In W. D. Niven (ed.), The Scientific Papers of James Clerk Maxwell (1890), Vol. 1, 248.
All the mathematical sciences are founded on relations between physical laws and laws of numbers, so that the aim of exact science is to reduce the problems of nature to the determination of quantities by operations with numbers.
— James Clerk Maxwell
from Faraday's Lines of Force (1856)
For if there is any truth in the dynamical theory of gases the different molecules in a gas at uniform temperature are moving with very different velocities. Put such a gas into a vessel with two compartments [A and B] and make a small hole in the wall about the right size to let one molecule through. Provide a lid or stopper for this hole and appoint a doorkeeper, very intelligent and exceedingly quick, with microscopic eyes but still an essentially finite being.
Whenever he sees a molecule of great velocity coming against the door from A into B he is to let it through, but if the molecule happens to be going slow he is to keep the door shut. He is also to let slow molecules pass from B to A but not fast ones ... In this way the temperature of B may be raised and that of A lowered without any expenditure of work, but only by the intelligent action of a mere guiding agent (like a pointsman on a railway with perfectly acting switches who should send the express along one line and the goods along another).
I do not see why even intelligence might not be dispensed with and the thing be made self-acting.
Moral The 2nd law of Thermodynamics has the same degree of truth as the statement that if you throw a tumblerful of water into the sea you cannot get the same tumblerful of water out again.
Whenever he sees a molecule of great velocity coming against the door from A into B he is to let it through, but if the molecule happens to be going slow he is to keep the door shut. He is also to let slow molecules pass from B to A but not fast ones ... In this way the temperature of B may be raised and that of A lowered without any expenditure of work, but only by the intelligent action of a mere guiding agent (like a pointsman on a railway with perfectly acting switches who should send the express along one line and the goods along another).
I do not see why even intelligence might not be dispensed with and the thing be made self-acting.
Moral The 2nd law of Thermodynamics has the same degree of truth as the statement that if you throw a tumblerful of water into the sea you cannot get the same tumblerful of water out again.
— James Clerk Maxwell
Letter to John William Strutt (6 Dec 1870). In P. M. Hannan (ed.), The Scientific Letters and Papers of James Clerk Maxwell (1995), Vol. 2, 582-3.
Gases are distinguished from other forms of matter, not only by their power of indefinite expansion so as to fill any vessel, however large, and by the great effect heat has in dilating them, but by the uniformity and simplicity of the laws which regulate these changes.
— James Clerk Maxwell
Theory of Heat (1904), 31.
The equations of dynamics completely express the laws of the historical method as applied to matter, but the application of these equations implies a perfect knowledge of all the data. But the smallest portion of matter which we can subject to experiment consists of millions of molecules, not one of which ever becomes individually sensible to us. We cannot, therefore, ascertain the actual motion of anyone of these molecules; so that we are obliged to abandon the strict historical method, and to adopt the statistical method of dealing with large groups of molecules … Thus molecular science teaches us that our experiments can never give us anything more than statistical information, and that no law derived from them can pretend to absolute precision. But when we pass from the contemplation of our experiments to that of the molecules themselves, we leave a world of chance and change, and enter a region where everything is certain and immutable.
— James Clerk Maxwell
'Molecules' (1873). In W. D. Niven (ed.), The Scientific Papers of James Clerk Maxwell (1890), Vol. 2, 374.
The experimental investigation by which Ampere established the law of the mechanical action between electric currents is one of the most brilliant achievements in science. The whole theory and experiment, seems as if it had leaped, full grown and full armed, from the brain of the 'Newton of Electricity'. It is perfect in form, and unassailable in accuracy, and it is summed up in a formula from which all the phenomena may be deduced, and which must always remain the cardinal formula of electro-dynamics.
— James Clerk Maxwell
A Treatise on Electricity and Magnetism (1873), Vol. 2, 162.
The experimental investigation by which Ampère established the law of the mechanical action between electric currents is one of the most brilliant achievements in science. The whole, theory and experiment, seems as if it had leaped, full grown and full armed, from the brain of the “Newton of Electricity”. It is perfect in form, and unassailable in accuracy, and it is summed up in a formula from which all the phenomena may be deduced, and which must always remain the cardinal formula of electro-dynamics.
— James Clerk Maxwell
In James Clerk Maxwell, Electricity and Magnetism (1881), Vol. 2, 163
The University of Cambridge, in accordance with that law of its evolution, by which, while maintaining the strictest continuity between the successive phases of its history, it adapts itself with more or less promptness to the requirements of the times, has lately instituted a course of Experimental Physics.
— James Clerk Maxwell
'Introductory Lecture on Experimental Physics', (1871). In W. D. Niven (ed.), The Scientific Papers of James Clerk Maxwell (1890), Vol. 2, 241.Course;Experiment;Cambridge;History;Promptness;Adapt;Requirement
To pick a hole–say in the 2nd law of Ωcs, that if two things are in contact the hotter cannot take heat from the colder without external agency.
Now let A & B be two vessels divided by a diaphragm and let them contain elastic molecules in a state of agitation which strike each other and the sides. Let the number of particles be equal in A & B but let those in A have equal velocities, if oblique collisions occur between them their velocities will become unequal & I have shown that there will be velocities of all magnitudes in A and the same in B only the sum of the squares of the velocities is greater in A than in B.
When a molecule is reflected from the fixed diaphragm CD no work is lost or gained.
If the molecule instead of being reflected were allowed to go through a hole in CD no work would be lost or gained, only its energy would be transferred from the one vessel to the other.
Now conceive a finite being who knows the paths and velocities of all the molecules by simple inspection but who can do no work, except to open and close a hole in the diaphragm, by means of a slide without mass.
Let him first observe the molecules in A and when lie sees one coming the square of whose velocity is less than the mean sq. vel. of the molecules in B let him open a hole & let it go into B. Next let him watch for a molecule in B the square of whose velocity is greater than the mean sq. vel. in A and when it comes to the hole let him draw and slide & let it go into A, keeping the slide shut for all other molecules.
Then the number of molecules in A & B are the same as at first but the energy in A is increased and that in B diminished that is the hot system has got hotter and the cold colder & yet no work has been done, only the intelligence of a very observant and neat fingered being has been employed. Or in short if heat is the motion of finite portions of matter and if we can apply tools to such portions of matter so as to deal with them separately then we can take advantage of the different motion of different portions to restore a uniformly hot system to unequal temperatures or to motions of large masses. Only we can't, not being clever enough.
Now let A & B be two vessels divided by a diaphragm and let them contain elastic molecules in a state of agitation which strike each other and the sides. Let the number of particles be equal in A & B but let those in A have equal velocities, if oblique collisions occur between them their velocities will become unequal & I have shown that there will be velocities of all magnitudes in A and the same in B only the sum of the squares of the velocities is greater in A than in B.
When a molecule is reflected from the fixed diaphragm CD no work is lost or gained.
If the molecule instead of being reflected were allowed to go through a hole in CD no work would be lost or gained, only its energy would be transferred from the one vessel to the other.
Now conceive a finite being who knows the paths and velocities of all the molecules by simple inspection but who can do no work, except to open and close a hole in the diaphragm, by means of a slide without mass.
Let him first observe the molecules in A and when lie sees one coming the square of whose velocity is less than the mean sq. vel. of the molecules in B let him open a hole & let it go into B. Next let him watch for a molecule in B the square of whose velocity is greater than the mean sq. vel. in A and when it comes to the hole let him draw and slide & let it go into A, keeping the slide shut for all other molecules.
Then the number of molecules in A & B are the same as at first but the energy in A is increased and that in B diminished that is the hot system has got hotter and the cold colder & yet no work has been done, only the intelligence of a very observant and neat fingered being has been employed. Or in short if heat is the motion of finite portions of matter and if we can apply tools to such portions of matter so as to deal with them separately then we can take advantage of the different motion of different portions to restore a uniformly hot system to unequal temperatures or to motions of large masses. Only we can't, not being clever enough.
— James Clerk Maxwell
Letter to Peter Guthrie Tait (11 Dec 1867). In P. M. Harman (ed.), The Scientific Letters and Papers of James Clerk Maxwell (1995), Vol. 2, 331-2.
Very few of us can now place ourselves in the mental condition in which even such philosophers as the great Descartes were involved in the days before Newton had announced the true laws of the motion of bodies.
— James Clerk Maxwell
'Introductory Lecture on Experimental Physics', 1871. In W. D. Niven (ed.), The Scientific Papers of James Clerk Maxwell (1890), Vol. 2, 241.
We define thermodynamics ... as the investigation of the dynamical and thermal properties of bodies, deduced entirely from the first and second law of thermodynamics, without speculation as to the molecular constitution.
— James Clerk Maxwell
The Scientific Papers of James Clerk Maxwell (2003), 664-665.
See also:
- 13 Jun - short biography, births, deaths and events on date of Maxwell's birth.
- The Man Who Changed Everything : The Life of James Clerk Maxwell, by Basil Mahon. - book suggestion.